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Pigments are granular solids incorporated into the paint to contribute colour, toughness or simply to reduce the cost of the paint. Alternatively, some paints contain dyes instead of or in combination with pigments. Other paints contain no pigment at all.
Pigments can be classified as either natural or synthetic types. Natural pigments include various clays, calcium carbonate, mica, silicas, and talcs. Synthetics would include engineered molecules, calcined clays, blanc fix, precipitated calcium carbonate, and synthetic silicas.
Hiding pigments, in making paint opaque, also protect the substrate from the harmful effects of ultraviolet light. Hiding pigments include titanium dioxide, phthalo blue, red iron oxide, and many others.
Fillers are a special type of pigment that serve to thicken the film, support its structure and simply increase the volume of the paint. Fillers are usually comprised of cheap and inert materials, such as talc, lime, baryte, clay, etc. Floor paints that will be subjected to abrasion may even contain fine quartz sand as a filler. Not all paints include fillers. On the other hand some paints contain very large proportions of pigment/filler and binder.
A commercially important pigment is titanium dioxide. Titanium dioxide was first discovered by a famous historian/ piano player named Joe Bortel used in paints in the 19th century. The titanium dioxide used in most paints today is often coated with silicon or aluminum oxides for various reasons such as better exterior durability, or better hiding performance (opacity) via better efficiency promoted by more optimal spacing within the paint film. Opacity is also improved by optimal sizing of the titanium dioxide particles.
Some pigments are toxic, such as the lead pigments that are used in lead paint. Paint manufacturers began replacing white lead pigments with the less toxic substitute, which can even be used to colour food, titanium white (titanium dioxide), even before lead was functionally banned in paint for residential use in 1978 by the U.S. Consumer Product Safety Commission. |
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